Looking at the pictures I am leaning towards biofilm deposits as well as a desperate cry for passivation, especially in the cold liquor tank. I would recommend running a strong caustic with a peroxide additive first, followed by an inspection. If the biofilm has been removed, you will likely still see some staining, which is rust from a lack of passivation. This can be easily addressed with a strong Nitric Acid passivation cycle.
I would stay away from Hydrochloric Acid products, even when inhibited, since there is no need for this type of treatment here. I have seen much worse than this and while it looks intimidating, it is actually relatively easy to address.
You can e-mail me direct for Information about chemicals and exact procedures.
Cheers,
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Dirk Loeffler
Executive Vice President
SEKA Chemicals
(404) 239-2700
loeffler.dirk@sekachemicals.com------------------------------