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residual CO2 level before CIP

  • 1.  residual CO2 level before CIP

    Posted 02-26-2024 18:37

    Hello everyone, 

    I was hoping someone might be able to tell me a recommended maximum ppm value of residual CO2 leftover in a brite tank or storage tank before it is safe to use a caustic wash via CIP? We do not want to risk implosion, or dilute the strength of our caustic cleaner.

    Most of the reading I have found just mention purging all the CO2 from the tank, but I was hoping to find out the true definition of "all". Right now we are purging our tanks with compressed air, but there is always a point at the end of the purge where we wonder if the ppm for CO2 has to be zero, or if we can cut it off at a certain point and continue on with the cleaning cycle. 

    Thank you!



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    Rachael Bepple
    Pacific Western Brewing Co
    Prince George BC
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  • 2.  RE: residual CO2 level before CIP

    Posted 02-27-2024 17:22

    I can't answer your specific question about target ppm levels, however, as it takes a lot of air volume to blow out a tank, years ago we started using a shop vac set to 'blow' and it works quite well for this task.  I imagine it's cheaper to run than an air compressor for the same job.



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    Tyson Arp
    Head Brewer
    Nebraska Brewing Company
    La Vista NE
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  • 3.  RE: residual CO2 level before CIP

    Posted 02-28-2024 15:20

    Hi Racheal,

    A couple thoughts without going through a lot of calculations.

    There is no "zero" CO2, because ambient air is 450 ppm+/-. Also, in the States, we have a workplace exposure limit (8-hr all day avg exposure without a respirator) of 5,000 ppm (0.5%). So, if simply for being able to open the manway and have your head near the opening, you'll want to be below 5,000. Canadian exposure limit is also 5,000 ppm (ACGIH).

    I know of breweries who make sure the CO2 is below 5,000 before they begin CIP based on the worker health measurement, and none have experienced tank collapse, to my knowledge. I think there is simply too little CO2 to result in sufficient vacuum pressures.

    In any case, you will need a CO2 meter to check your tank bleeding process to learn what sort of procedure and time will be required.



    ------------------------------
    Matt Stinchfield
    Author "Brewery Safety: Principles, Processes and People"
    BA Safety Subcommittee
    Safety Coach
    Guilford, VT
    802-258-8748
    ------------------------------



  • 4.  RE: residual CO2 level before CIP

    Posted 03-01-2024 14:55

    I don't know if you have ever done this, but putting your head into a tank with 5000 ppm CO2 is not something I would recommend. That 5000 ppm 8 hr max number is to prevent injury over time, but I have found levels of 1,500 or more can be detrimental to working conditions: headaches, angriness and shortness of breath are commonly observed. Due to these observations, we take additional actions (increased fan velocities, opening doors, etc) whenever levels exceed 1,500 ppm. Typically this will occur during longer can runs, tank purging, and filling of the outside CO2 dewar.



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    Alexander Kopf
    Brewer
    Northwoods Brewing Company
    alex@northwoodsbrewingcompany.com
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  • 5.  RE: residual CO2 level before CIP

    Posted 03-01-2024 16:53
    One should avoid sticking one's head in a tank. A tank is confined permit-required space.

    Sent from Samsung Galaxy smartphone.
    Get Outlook for Android



    This e-mail message was sent from a retired or emeritus status employee of West Chester University.





  • 6.  RE: residual CO2 level before CIP

    Posted 03-04-2024 14:18
      |   view attached

    A while ago at the brewery I worked for, the workers comp insurance safety rep was explaining confined spaces and safe tank entry to us and how you don't even have to enter one to injure yourself. She told me a story about a worker who stuck his head through a tank side door to retrieve a stand pipe. The tank was full of CO2 and in breathing it in his head instinctively retracted upwards, hitting it on the inside of the door. He collapsed and asphyxiated without even entering the tank. Please don't test for CO2 in tanks by placing your head inside.

     

    I think the shop-vac reverse-flow blower into the tank door trick is a very good one, adding a large volume of air into the tank will quickly evacuate the CO2 gas (depending on the tank size). But you also need to be aware that this is flushing large amounts of CO2 into the cellar area, so make sure you have a fresh air source for your workspaces.

     

    I don't advise depending on the pressure-vacuum relief equipment to solve the CO2-Caustic vacuum issue in protecting tanks. Beer tanks are fairly weak to negative pressure and these devices are usually way undersized to cope with the large surge in vacuum pressure which can result in this chemical reaction and can implode tank. Instead blow-down any positive pressure in the tank to outside of the building, blow-out residual CO2 with a blower and ventilate the tank well while you give it a warm (not hot) pre-rinse. The warm temperature rinse will increase the pressure in the tank and help push out the remaining gas to a level that will work for caustic without implosion danger or waste. Best practice with a side entry door is to open the door, take off the door gasket, rinse it, then drape it on the door hinge while loosely closing the door as pictured in the attachment. This will provide a high level of ventilation during rinses and CIP.

     

    Cheers,

     

    Karl

     

    Consulting Brewer

    Author of The Craft Brewer's Guide to Best Practices

    Karl Ockert Brewing Services LLC

    www.ockertbrewserv.com

    Cell:  503-887-1938

     






  • 7.  RE: residual CO2 level before CIP

    Posted 03-01-2024 18:46

    Hi Matt, thank you so much for the response. That makes a lot of sense that most breweries would vent until below the 8hr exposure limit, and that is also good to hear that this number could potentially be a good baseline for the start of a CIP and not experience tank collapse. 

    For clarification, both to you and the group, we are currently using practices to make sure that the atmosphere is safe for workers before opening up the tank. This involves blowing out with compressed air, but unfortunately it can take a long time, especially on our bigger 450hL tanks. I received more clarification from my team about this question, and we were hoping to find out if anyone knew what max level of CO2 could still remain in a tank before CIP could be started, without risking implosion. This would ideally be on a tank that we did not have to open up. The only opening would be the atmosphere lines, but we would like to keep the door closed. The idea is to not let CO2 out into the cellar to raise any atmosphere levels, while also cutting down time on purging with air. Any help is greatly appreciated! Thank you so much!



    ------------------------------
    Rachael Bepple
    Pacific Western Brewing Co
    Prince George BC
    ------------------------------



  • 8.  RE: residual CO2 level before CIP

    Posted 03-04-2024 20:19

    The risk of tank implosion and/or reducing the effectiveness of the caustic cleaning solution can be eliminated by using acidic detergents to clean tanks with low soil levels. Considerable savings in time can be achieved - the tanks will be available sooner and there will be savings in CO2 used to purge air before refilling. An occasional clean using caustic (say every 3 months), which will require the removal of most of the CO2 before cleaning, will remove any organic soils that have developed.



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    Richard Rench
    Oakville ON
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  • 9.  RE: residual CO2 level before CIP

    Posted 02-28-2024 17:54

    Hi Rachael,

    As long as your tank has adequate vacuum relief (open ports, cracked or open manway, racking arm removed and port left open, etc.) you should not be at risk for imploding your storage tanks regardless of residual CO2.

    As far as your caustic becoming diluted by CO2, your caustic solution will lose strength if there is any amount of residual CO2. However, it's up to you to determine what is acceptable for your brewery's standards. You could try running some trials to determine at what point your tanks still come clean. I would recommend titrating your caustic solution during a normal CIP. Then, reduce your blow-out time by 20-25%, run a CIP cycle and titrate again. Then you can compare titration results to see how much your caustic strength was reduced, and confirm cleanliness using an ATP meter swab. Then you can reduce your blow-out time further if you're satisfied with your results. 

    Alternatively, if you're still determined to blow out all of the CO2, you can attach a gas flow meter to your off-gassing port and make sure you blow out the entire volume of the tank.

    I hope this helps!



    ------------------------------
    Kaitlin Beaucage
    Brewer II
    Allagash Brewing Company
    Portland ME
    (207) 878-5385
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  • 10.  RE: residual CO2 level before CIP

    Posted 02-28-2024 15:19

    First we hot-rinse our tanks to remove physical debris and trub. Similar to Tyson Arp, we use a blower pump to force outside air into the tank through the CIP or vent arm through the top of the tank that pushes CO2 out of the cone at the bottom and through a hose to evacuate outside. We monitor CO2 levels until we drop below 5000 ppm and then proceed with CIP-ing the tank. Our tanks range from 50bbl - 125bbl and our blower system doesn't take any longer than 30 minutes to fully blow-down a tank to this 5000 ppm level.



    ------------------------------
    Dakota Soule
    Production Manager
    Upper Hand Brewery
    Escanaba MI
    (906) 233-5003
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  • 11.  RE: residual CO2 level before CIP

    Posted 02-28-2024 15:42

    The issues of CO2 and CIP are from the reaction NaOH(aq) + CO2(g) --> NaHCO3(aq).

    (aq) means water solution (g) means gas. The two effects are:

    Loss of CO2, hence possible vacuum.

    Loss of NaOH (caustic) hence ineffective CIP.

    Neither of these are problems at ppm level. Purging to 5% v/v should be fine. 

    Be careful about the CO2. TLV is 0.5%. It would be good to carry the CO2 generated by the purge to the outside.



    ------------------------------
    Roger Barth
    Author (with M Farber) of Mastering Brewing Science ISBN 9781119456056
    Retired
    West Chester PA
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  • 12.  RE: residual CO2 level before CIP

    Posted 03-05-2024 21:07

    Seeing lots of good focus on safety in the comments, which is great to read. 

    We have tanks ranging from 30 BBL to 600 BBL, and then more in the 1500 BBL range. 

    For the smaller range of tanks (30-600) we have an established practice of using a large air-blower pump, mounted on a cart for convenience, which blows outside air into the tank top via the Vent arm. The exhaust is out all available holes in the tank bottom (racking arm, sample port, cone outlet), and into the cellar where we operate. We have atmospheric sensors and exhaust fans if the ambient CO2 levels rise above a certain safety range. 

    Since we were a smaller pub we've utilized handheld Oxygen meters (Dräger makes ours) to determine when the ambient Oxygen levels return to the tank interior. Similarly, we used to use these to know when a tank was purged of Oxygen before filling. I believe 21% O2 is typical. Takes maybe an hour for those 600 BBL tanks using our pumps. 

    Based on the nature of our atmosphere, I would not shoot for zero CO2 as it is not possible, but encourage you to try using a O2 meter to establish a system of standard times for airing out the tanks prior to CIP. 



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    Aaron Rossell
    Lead Cellar Operator
    Grand Rapids MI
    Founders Brewing CoFounders Brewing CoAaron
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