Hi Adrian,
Controlling the intensity and length of the boil is a good way to reduce costs, produce more stable wort and and an overall more sustainable product.
A first step, if not done already, would be calculating the appropriate level of steam flow/pressure/temperature relative to your kettle heating jacket area and target evaporation. You can then ensure that this at least sense-checks with modern brewing standards (Steam/Wort ΔT = <15°C, 4-7% Evaporation/hr).
In terms of assays, Coagulable Nitrogen, Thiobarbituric Acid Index and DMS are all likely useful analyses in confirming both the baseline and the impact of any changes. When stripping volatiles, two phase flow of liquid and gas is what drives DMS off, so in theory any change in evaporation may have an impact on your DMS levels though as others have said, it depends on the beer style and the pre-cursors in your raw materials.
Cheers and good luck!
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Wilson Hede
Jing-A Brewing
Beijing, China
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