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Husk Tannin Extraction During Decoction

  • 1.  Husk Tannin Extraction During Decoction

    Posted 03-11-2024 18:00

    Whenever I read or hear about decoction mashing, the issue of husk tannin extraction doesn't seem to come up and the impression that I get is that we don't need to worry about it. Why is it, though, that we don't need to worry about extracting tannins from husk when we're boiling a portion of the mash for up to 45 minutes, but we do need to worry about tannin extraction if we sparge above 172°F? I've gone through Noonan's New Brewing Lager Beer and this question isn't addressed. Any knowledge you have on this would be greatly appreciated!



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    Nassim Sultan
    Brewer/Free Agent
    nassimsultan@gmail.com
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  • 2.  RE: Husk Tannin Extraction During Decoction

    Posted 03-12-2024 14:52
    I'd expect that it occurs, but is not significant because of the pH.  Tannin extraction occurs or increases at the end of sparging because the pH rises as the mash thins.  I've not had problems with triple, or fewer, decoctions.

    Prost






  • 3.  RE: Husk Tannin Extraction During Decoction

    Posted 03-12-2024 15:57

    That makes sense! Your response is a great reminder that low pH is an important factor in husk extraction during sparge--not just temperature. 



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    Nassim Sultan
    Brewer/Free Agent
    nassimsultan@gmail.com
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  • 4.  RE: Husk Tannin Extraction During Decoction

    Posted 03-14-2024 19:10

    Has anyone ever measured Proteins / Free nitrogen of infusion vs. Decoction? 

    At the lower pH, the isoelectric point of the proteins may also be  finning out the increased tannins.



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    John Frederick
    Principal Product and Process Innovator
    Gallo
    Modesto CA
    (209) 604-5246
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  • 5.  RE: Husk Tannin Extraction During Decoction
    Best Answer

    Posted 03-14-2024 07:09

    Hi Nassim,
    The book New Brewing Lager Beer does mention astringency extraction on page 136. But Noonan only discusses this issue in a small section: "probably because the density and pH of the decoction prevents phenols from being leached out of the husks." Therefore, I believe the reason is for sure low pH due to concentrated wort compared to the wort during boiling. 



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    Asher Sun
    Brewer
    Drake's Brewing
    Sunnyvale CA
    (805) 680-9711
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  • 6.  RE: Husk Tannin Extraction During Decoction

    Posted 03-14-2024 10:53

    That quote is a great find, thanks for sharing! It does certainly seem that the critical factor is pH. It's also interesting, though, that Noonan uses "probably", and I wonder why he wasn't totally sure when he wrote New Brewing Lager Beer. To be clear, I do not mean that as a criticism of Greg Noonan at all. Instead, his use of "probably" makes me wonder if there has been any research on this topic since New Brewing Lager Beer was published 20 years ago. 



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    Nassim Sultan
    Brewer/Free Agent
    nassimsultan@gmail.com
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  • 7.  RE: Husk Tannin Extraction During Decoction

    Posted 03-14-2024 15:11
    I'm no chemist and certainly without Noonan's expertise, but density seems an unlikely contributor.  Compare homebrewer process to commercial, where homebrewers tend to take thick decoctions, while commercial decoctions are taken from a more homogenized mash to support pumping.  Neither suffer from noticable tannins.

    Beyond pH, I'd guess that the composition of water minerals is also a contributor; Na/NaCl for example.

    Prost






  • 8.  RE: Husk Tannin Extraction During Decoction

    Posted 03-15-2024 14:47

    Probably a good idea to read through this older article; https://www.mbaa.com/publications/tq/tqPastIssues/1967/Documents/4_98.pdf

    Cheers, Keith



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    Keith Armstrong
    Retired
    Edmonton AB
    (780) 504-4245
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  • 9.  RE: Husk Tannin Extraction During Decoction

    Posted 03-19-2024 11:57

    I also must question Noonan's interpretation.  M. Jurkova et al. (J Inst Brewing, 2012) found that decoction mashes actually did extract more polyphenols than infusion mashes.  And through my own research I have found that total polyphenol concentration in fact decreases over the course of the lauter (though the ratio of polyphenols to extract increases.)  Not that I doubt the findings of Schuster and Raab regarding "herbstoffe", cited in Mr. Armstrong's reference. The only myth I'm here to bust is the notion that the role of malt-derived polyphenols is simple.  A review of the literature shows the many different types of polyphenols in wort, and their various tendencies to form trub/break, impart bitter and stale flavors, lead to chill haze, protect the beer from oxidation, and contribute to mouth-feel.  I think Mr. Heasley's answer is credible, but Mr. Sultan's question remains a good one.



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    Cullen Dwyer
    Brewer/Cellar/QA
    Finestkind Brewing
    Westminster MA
    (978) 874-9965x1160
    Brewer/Cellar/QAFinestkind BrewingFinestkind BrewingBrewer/Cellar/QABrewer/Cellar/QA
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  • 10.  RE: Husk Tannin Extraction During Decoction

    Posted 03-19-2024 13:15

    Yes, indeed. It's complicated.

    I'd suggest you inform yourself and your teams by doing more tasting.

    Pilot/bench-top experiments can be combined with sensory to elucidate quite a bit of what is good and bad about astringency.

    The 1967 article points clearly to things not being simple.

    Cheers, Keith



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    Keith Armstrong
    Retired
    Edmonton AB
    (780) 504-4245
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