Dear Katherine,
I always thought the future of the ASBC would be to create User Groups to answer your post. We need an Anton Paar Group. There's enough of us, already.
I waited for some ASBC 'A-lister' like Greg Casey or Gary Spedding or the aforementioned Alex Speers to reply; but in their absence, I'll weigh in as a journeyman analytical technician working in the greatest industry on earth. I'm never going back to hazardous waste characterization. God Bless that Cullen Dwyer, but I'll push you where you need to go.
The Anton Paar suite of instrumentation is my ATM machine. My kids are going to Oregon State on its reproducibility and resolution. It's your job to master the idiosyncracies of the Austrian mindset.
Understand what you bought- a Near InfraRed measurement/exquisite algorithm of ethanol in malted beverages (for the Beer Analyzer.) Although, note that methanol and isopropanol will positively interfere with the algorithm. Really, what you've bought is a fine temperature control of density with the DMA4500.
Rely on density. It will never let you down, but you need to build robust datasets to tame the inevitable random error. Remember, you are working with a tripartite solution in finished beer; ethanol, water and everything left behind.
1) Do a Gage Reproducibility and Reliability with everyone who relies on these data to make decisions: brewers, cellar staff, managers, you. It is absolutely critical to get buy-in by your team to master the investment and create a culture where folks want the instrument to work. Have everyone run 10 samples- Anton Paar and hydrometer.
Those knuckle-draggin' brewers who swear by their hydrometers, can they control temp to 0.1°C? Get the data: run 10 Anton Paar samples and 10 with their hydrometer. Chart the results with coefficients of variance. Let the chips fall where they may.
2) Run pre-pitch wort samples the same way. You may need to centrifuge to finish the hot trub precipitation. Get everyone to run the instrument. You all have to make that instrument your own and make it pay.
3) You: distill samples until you have confidence that you can sell the NIR results to your team. We distilled alcohols until the power company thought we were drawing so much power that we HAD to be doing something illegal.
Distilling is the reference method and can tell you if/when an interference from turbidity is significant. I don't filter, except under duress. I will centrifuge, as needed.
4) Never give in. We all use Anton Paar, and/or Kyoto and/or whatever Chinese upstart is on the horizon. The fundamentals are well observed- control temperature, get some way to measure density and ethanol and you will rule the world.
Beat those who claim that a hydrometer is superior with a stick.
Scott
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Scott Bruslind
Laboratory Manager
Analysis Laboratory
Lebanon OR
(541) 451-8571
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Original Message:
Sent: 07-25-2017 16:27
From: Katherine Steblenko
Subject: DMA OGs vs Brewhouse Hydrometer
Is anyone else using a DMA 4500 M Alcolyzer Beer ME? We've been using ours for almost 2 years now, and we use it every day to check our final product. It works beautifully for alcohol and final gravity, with a very high level of reproducibility. We've noticed, however, that the calculated OGs it spits out are off by about 0.5 Plato from what the brewers were reading on our calibrated hydrometers. Certain brands seem to be a bit further off than others as well.
We weren't sure where in the process the misstep was, so we began running every single hydrometer sample run by the brewers through the DMA. We ran over 200 samples and the majority of the time got a higher reading on our hydrometers, with most of them being over 0.1P off. The German calibrated hydrometers were definitely closer than the cheaper ones, but we were seeing differences upwards of 0.5P between the readings, which is beyond human error. Meanwhile, some samples were exactly the same, to the hundredths place. We would occasionally see numbers in the ABV section during this, which was strange, as they were pre-yeast.
The beers we ran these tests on are finishing up in the fermenters, and I've been able to compare the calculated OGs from the DMA from the OG it read itself out of the HX, and the calculated is higher than the original read. We have a bit longer to wait for more data though.
All of our FGs match, alcohol is on point, but for some reason this OG calculation isn't working out. We've also struggled with any beer that has appreciable haze, and find that filtering/centrifuging will give us different alcohol levels. I'm assuming this is because the alcohol module in the DMA is based in spectrophotometry the haze is interfering?
Has anyone else had trouble with any of these issues? We're not sure which numbers to trust anymore, as the further we look into this, the less sense it makes. This has happened despite all checks and calibrations being passed, proper daily cleaning regimens being followed, and extensive conversations with Anton-Paar. I'm out of ideas and would love any input fellow QC folks have. We're trying to dial in our recipes further and it's difficult when you can't trust your OGs.
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Kate Steblenko
Quality Scientist
Jack's Abby Craft Lagers
Framingham MA
(508) 872-9000
kates@jacksabby.com
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